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物理化學(三) Physical Chemistry III - 單元一 Molecular energy levels for macroscopic thermodynamics Introduction Quantum statistic mechanics Simple translational, rotational, and vibrational models Partition function

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單元一 Molecular energy levels for macroscopic thermodynamics
Introduction
Quantum statistic mechanics
Simple translational, rotational, and vibrational models
Partition function
單元二 Equilibrium statistical mechanics I. Probability distribution
Most probable distribution
The molecular partition function
Translational partition function
Rotational partition function
Vibrational partition function
Electronic partition function
Partition function for polyatomic molecule
Number of translational states*
單元三 Equilibrium statistical mechanicsII Statistical thermodynamics
Entropy
Pressure
State functions
Calculation of internal energy
Partition function of Van der Waals equation*
Calculation example
Chemical equilibrium
Chemical reaction for triatomic system
Arrhenius formula
單元四 Equilibrium statistical mechanics III. Ensembles
Canonical ensemble
Classical statistical mechanics
Dense gases
Liquids
單元五 The structure of solids, liquids, and polymers
Crystal Vibration
Free electron theory
From solid to liquid
Polymer conformation
單元六 The kinetic theory of gases
The velocity probability distribution
Radial distribution molecular speed
Pressure, effusion and collision
Potential energy
Molecular collisions in a hard-sphere gas
單元七 The rates of chemical reactions
Chemical reaction rate
Forward reaction with one reactant
Forward reaction with two reactants
Including reverse reaction
Competing reactions
單元八 The chemical reaction mechanisms
Collision theory of bimolecular reactions
Arrhenius formula (again)
Fraction number in bimolecular reactions
Unimolecular reactions
Two-step reactions
More than two-step reactions
Chain reactions
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